Quick Comparison

Azelaic AcidPanthenol (Pro-Vitamin B5)
Typical ConcentrationOTC: 10% (The Ordinary). Prescription: 15% gel (Finacea for rosacea), 20% cream (Azelex for acne). Apply twice daily. Well-tolerated but may sting/itch initially. Full effects at 8-12 weeks.Concentrations: 1-5% in most products. Up to 5% in healing/repair formulations. Apply morning and night. Safe for all skin types, including very sensitive and compromised skin. No usage limits.
ApplicationTopical (gel, cream, serum). Slightly gritty texture in some formulations. Apply to clean skin.Topical (cream, serum, lotion, ointment). Compatible with all other skincare ingredients.
Research Papers9 papers10 papers
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Mechanism of Action

Azelaic Acid

Azelaic acid exhibits multi-modal activity: (1) Tyrosinase inhibition—competitively inhibits tyrosinase selectively in hyperactive melanocytes (melasma, PIH) while sparing normal ones; may involve mitochondrial enzyme interference in dysregulated melanocytes. (2) Antimicrobial—bacteriostatic against Cutibacterium acnes by inhibiting bacterial protein synthesis. (3) Comedolytic—normalizes follicular keratinization, reducing hyperkeratinization and corneocyte cohesion; may modulate keratinocyte differentiation. (4) Anti-inflammatory—scavenges ROS, inhibits neutrophil free radicals, reduces pro-inflammatory cytokines. Inhibits 5-alpha-reductase in sebocytes, potentially reducing sebum. Multi-pathway activity explains efficacy in acne, rosacea, and hyperpigmentation. Safe during pregnancy.

Panthenol (Pro-Vitamin B5)

Panthenol (D-pantothenic acid alcohol) penetrates the stratum corneum and is converted to pantothenic acid (vitamin B5) by pantetheinase and alkaline phosphatase enzymes in the skin. Pantothenic acid is a precursor to coenzyme A (CoA), which is required for the synthesis of fatty acids (via acetyl-CoA carboxylase and fatty acid synthase) that form the ceramides, cholesterol, and free fatty acids of the stratum corneum lipid barrier. This supports barrier repair, improves lamellar structure, and reduces transepidermal water loss (TEWL). Panthenol has direct humectant properties—its hydroxyl groups attract and bind water in the stratum corneum. It stimulates fibroblast proliferation and migration, accelerating wound healing and re-epithelialization. Panthenol may also have mild anti-inflammatory effects. As a provitamin, it is stable in formulations and well-tolerated. The Bepanthen/Bepanthol healing creams leverage these mechanisms for wound care and barrier repair.

Risks & Safety

Azelaic Acid

Common

Stinging, burning, itching on initial application (usually subsides within 2 weeks). Mild dryness.

Serious

None. Safe during pregnancy and breastfeeding.

Rare

Allergic contact dermatitis, hypopigmentation (rare at cosmetic concentrations).

Panthenol (Pro-Vitamin B5)

Common

None — extremely well-tolerated.

Serious

None. One of the safest skincare ingredients available.

Rare

Contact allergy is extremely rare.

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