Quick Comparison

BakuchiolMatrixyl (Palmitoyl Pentapeptide-4)
Typical ConcentrationConcentrations: 0.5%-2%. Can be used morning and/or night (not photosensitizing like retinoids). Apply after cleansing. Can be combined with retinoids for enhanced effects. Safe to use without SPF specifically for this ingredient, though daily SPF is always recommended.Typically used at 2-8% in formulations. Applied morning and/or night. Compatible with virtually all other active ingredients. Often found combined with Matrixyl 3000 (palmitoyl tripeptide-1 + palmitoyl tetrapeptide-7) for enhanced effects.
ApplicationTopical (serum, oil, cream). Stable in formulation. Not photosensitizing.Topical (serum, cream). Water-soluble base. Apply to clean skin. Compatible with acids, retinoids, and vitamin C.
Research Papers10 papers2 papers
Categories

Mechanism of Action

Bakuchiol

Bakuchiol (meroterpene from Psoralea corylifolia) achieves retinol-like effects through RAR/RXR-independent pathways. It upregulates collagen I and III in fibroblasts via TGF-beta/Smad signaling and possibly ER-beta cross-talk. Bakuchiol downregulates MMP-1, preserving dermal collagen. It accelerates keratinocyte differentiation and stratum corneum turnover through distinct pathways. Direct antioxidant activity scavenges ROS and inhibits lipid peroxidation. Anti-inflammatory effects may involve NF-kappaB modulation. Clinical studies show comparable wrinkle reduction to 0.5% retinol; combination with retinol shows synergy. Safe during pregnancy—does not activate retinoic acid receptors.

Matrixyl (Palmitoyl Pentapeptide-4)

Matrixyl (palmitoyl pentapeptide-4, Pal-KTTKS) is a matrikine—a bioactive collagen fragment mimicking Lys-Thr-Thr-Lys-Ser from the alpha-1 chain of collagen I. This sequence binds integrin receptors on dermal fibroblasts, triggering TGF-beta/Smad and MAPK/ERK signaling that upregulates ECM synthesis genes. Fibroblasts increase production of collagen I, III, IV, fibronectin, elastin, and glycosaminoglycans including hyaluronic acid—recreating the wound-healing signal without tissue damage. The C16 palmitoyl chain enhances lipophilicity and stratum corneum penetration via intercellular lipid partitioning. Unlike retinoids, Matrixyl does not accelerate epidermal turnover, explaining its lack of irritation. Clinical studies show wrinkle reduction comparable to retinol.

Risks & Safety

Bakuchiol

Common

Very few — bakuchiol is exceptionally well-tolerated. Mild tingling in some users initially.

Serious

None documented. Safe during pregnancy.

Rare

Allergic reaction (rare plant allergy).

Matrixyl (Palmitoyl Pentapeptide-4)

Common

Essentially none — peptides are extremely well-tolerated.

Serious

None documented. Safe in pregnancy.

Rare

Minimal risk of allergic reaction.

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