Quick Comparison

Centella AsiaticaMatrixyl (Palmitoyl Pentapeptide-4)
Typical ConcentrationUsed in various forms: full extract, TECA (Titrated Extract of Centella Asiatica — a standardized blend of the four key actives), or individual compounds. Concentrations vary widely (0.1-5% of active compounds). Apply morning and/or night. Safe for daily use on all skin types.Typically used at 2-8% in formulations. Applied morning and/or night. Compatible with virtually all other active ingredients. Often found combined with Matrixyl 3000 (palmitoyl tripeptide-1 + palmitoyl tetrapeptide-7) for enhanced effects.
ApplicationTopical (serum, cream, toner, mask). TECA or pure centella extract preferred over whole plant extract for consistency.Topical (serum, cream). Water-soluble base. Apply to clean skin. Compatible with acids, retinoids, and vitamin C.
Research Papers10 papers2 papers
Categories

Mechanism of Action

Centella Asiatica

The four key triterpenoid saponins—madecassoside, asiaticoside, madecassic acid, and asiatic acid—exert distinct but complementary mechanisms. Madecassoside and asiaticoside are anti-inflammatory: they inhibit NF-κB nuclear translocation and IκB kinase activity, reducing TNF-α, IL-6, and IL-1β production in keratinocytes and dermal cells. Madecassic acid and asiatic acid (the aglycone forms) stimulate type I and III collagen synthesis in fibroblasts by upregulating collagen gene expression and procollagen production. All four compounds promote wound healing by stimulating angiogenesis via VEGF (vascular endothelial growth factor) upregulation, fibroblast proliferation and migration, and extracellular matrix remodeling. Centella extracts also increase superoxide dismutase (SOD) and catalase activity in skin cells, enhancing endogenous antioxidant defense. The triterpenes may modulate TGF-β and Smad signaling. TECA (Titrated Extract of Centella Asiatica) standardizes these actives for consistent clinical efficacy.

Matrixyl (Palmitoyl Pentapeptide-4)

Matrixyl (palmitoyl pentapeptide-4, Pal-KTTKS) is a matrikine—a bioactive collagen fragment mimicking Lys-Thr-Thr-Lys-Ser from the alpha-1 chain of collagen I. This sequence binds integrin receptors on dermal fibroblasts, triggering TGF-beta/Smad and MAPK/ERK signaling that upregulates ECM synthesis genes. Fibroblasts increase production of collagen I, III, IV, fibronectin, elastin, and glycosaminoglycans including hyaluronic acid—recreating the wound-healing signal without tissue damage. The C16 palmitoyl chain enhances lipophilicity and stratum corneum penetration via intercellular lipid partitioning. Unlike retinoids, Matrixyl does not accelerate epidermal turnover, explaining its lack of irritation. Clinical studies show wrinkle reduction comparable to retinol.

Risks & Safety

Centella Asiatica

Common

Very well-tolerated. Occasionally mild tingling.

Serious

None documented.

Rare

Allergic contact dermatitis (uncommon). Purified extracts are less likely to cause reactions than crude extracts.

Matrixyl (Palmitoyl Pentapeptide-4)

Common

Essentially none — peptides are extremely well-tolerated.

Serious

None documented. Safe in pregnancy.

Rare

Minimal risk of allergic reaction.

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